Achmad Chafidz, R.M. Faisal, Mujtahid Kaavessina, Dhoni Hartanto
Polypropylene(PP)/nanoclay composites samples have been fabricated by melt compounding the PP pellets with nanoclay masterbatch (i.e. 50 wt% of nanoclay) using a mini extruder. The effect of three loadings of nanoclay (i.e. 5, 10, and 15 wt%) on the morphology, nonisothermal crystallization, and viscoelastic behavior of the PP/nanoclay composites were investigated. All the nanocomposites samples were characterized by using Scanning Electron Microscope (SEM), Differential Scanning Calorimetry (DSC), and an oscillatory rheometer. The SEM results showed that the distribution of nanoclay in the PP was relatively good at all level of loadings. The DSC analysis results showed that the nanoclay has dramatically enhanced the crystallization temperature, from 117°C (for neat PP) to 127-129°C (for nanocomposites). Additionally, the frequency sweep test results exhibited that the presence of nanoclay increased the viscoelastic behavior of the PP matrix. © 2018 Trans Tech Publications, Switzerland.
Department of Chemical Engineering, Universitas Islam Indonesia, Yogyakarta, 55584, Indonesia; Department of Chemical Engineering, Universitas Sebelas Maret, Surakarta, 57126, Indonesia; Department of Chemical Engineering, Universitas Negeri Semarang, Semarang, 50229, Indonesia
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